Conference abstracts

On this page the abstracts are published of all lectures and posters presented at Frontiers in Chemistry, Armenia 2013. In the author list the presenting author is underlined.

Plenary lectures

Mastering complexity: functional supramolecular systems

ACF2013 P1    (PDF)

Bert Meijer

Highly Selective Catalytic Syntheses of Heterocyclic Compounds

ACF2013 P2    (PDF)

Michael P. Doyle

Taking Risks in Complex Synthesis Design

ACF2013 P3    (PDF)

Erik J. Sorensen

Catalysis: An Enabling Technology for a Sustainable Development in the 21th Century

ACF2013 P4    (PDF)

Matthias Beller

Hard and soft luminescent materials. Properties and applications

ACF2013 P5    (PDF)

Luisa De Cola

The Art of Perception in Organic Synthesis. From Mind's Eye to Practice

ACF2013 P6    (PDF)

Stephen Hanessian

Chiral Diene Ligands for Asymmetric Catalysis

ACF2013 P7    (PDF)

Tamio Hayashi

A Quantitative Approach to Polar Organic Reactivity

ACF2013 P8    (PDF)

Herbert Mayr

Chemical biology of the genome

ACF2013 P9    (PDF)

Shankar Balasubramanian

Complex Natural Products as a Driving Force for Discovery in Organic Chemistry

ACF2013 P10    (PDF)

Brian Stoltz

Cooperative Function in Atomically Precise Nanoscale Assemblies

ACF2013 P11    (PDF)

Paul S. Weiss

Chemistry of Organic Solar Cells

ACF2013 P12    (PDF)

Eiichi Nakamura

Keynote lectures

Exploring Chemoselectivity through Natural Product Total Synthesis

ACF2013 K1    (PDF)

Scott A. Snyder

Asymmetric Catalysis of Designer Chiral Organic Ion Pairs

ACF2013 K2    (PDF)

Takashi Ooi

Peptides as Asymmetric Catalysts

ACF2013 K3    (PDF)

Helma Wennemers

Renaissance of early main group organometallic chemistry

ACF2013 K4    (PDF)

Sjoerd Harder

Sugars & proteins: towards a synthetic biology

ACF2013 K5    (PDF)

Benjamin G. Davis

Stereoselective synthesis & catalysis with metal carbenes

ACF2013 K6    (PDF)

Jérôme Lacour

Rare-earth complexes for catalytic formation of C-C, C-N and C-P bonds

ACF2013 K7    (PDF)

Alexander A. Trifonov

Contributed lectures

Isomerization of Epoxides by a [Pd—H] Catalyst: a Combined Experimental and Theoretical Mechanistic Study

ACF2013 C1    (PDF)

Devendra J. Vyas, Evgeny Larionov, Clément Mazet

New approach for the synthesis of organofluorine compounds containing CF2 fragment

ACF2013 C2    (PDF)

Alexander D. Dilman, Vitalij V. Levin, Artem A. Zemtsov, Mikhail D. Kosobokov

First Asymmetric Syntheses of Three GlaxoSmithKline's Highly Potent Rolipram Analogues

ACF2013 C3    (PDF)

A. Yu. Sukhorukov, Y. D. Boyko, P. A. Zhmurov, S. L. Ioffe, V. A. Tartakovsky

Organo-Inorganic Hybrids: Design of Novel Molecular Recognition and Biocatalytic Nanomaterials

ACF2013 C4    (PDF)

Alessandro Cumbo, Philippe F.-X. Corvini, Patrick Shahgaldian

Synthetic and Mechanistic Studies on the Pd-Catalyzed C(sp3)—H γ-Arylation of Amino Acid Derivatives with Aryl Iodides

ACF2013 C5    (PDF)

M. Ángeles Fernández-Ibáñez, Inés Alonso, Ana Poveda, Juan C. Carretero

Exploiting "micron" superhydrophobicity

ACF2013 C6    (PDF)

Hidehiko Asanuma, Takashi Nakanishi, Andre Skirtach, Helmuth Möhwald

Crystallization-induced Deracemisation of P-stereogenic Phosphine Oxides

ACF2013 C7    (PDF)

Felix A. Kortmann, Erik P. A. Couzijn, Adriaan J. Minnaard

Zinc(II)-Amine Catalyzed Enantioselective Hydrosilylation

ACF2013 C8    (PDF)

Jadwiga Gajewy, Marcin Kwit

Enantioselective Michael Addition of Isocyanoactate to Vinyl Selenone: Access to α-Quaternary Amino Acids

ACF2013 C9    (PDF)

Thomas Buyck, Qian Wang, Jieping Zhu

Development and Scale-Up of an Optimized Route to the ALK Inhibitor CEP-28122

ACF2013 C10    (PDF)

Roger P. Bakale, Shawn P. Allwein, Renee C. Roemmele, James J. Haley, Jr., Dale R. Mowrey, Daniel E. Petrillo, James J. Reif, Diane E. Gingrich

Catalytic Alkylation of Nucleic Acids

ACF2013 C11    (PDF)

Dennis Gillingham

Fe-Catalyzed Oxidative C(3)-Functionalization of Amines

ACF2013 C12    (PDF)

Kounosuke Oisaki, Noriaki Takasu, Motomu Kanai

Biomolecular Structure and Dynamics through the Synergy of Experiment and Computation

ACF2013 C13    (PDF)

Aleksandr B. Sahakyan

Solvent-free synthesis of substituted pyrroles via multicomponent reaction of primary amines

ACF2013 C14    (PDF)

Zinatossadat Hossaini, Faramarz Rostami-Charati

De Novo Design of Novel Aspartic Protease Inhibitors Exploiting Dynamic Combinatorial Chemistry

ACF2013 C15    (PDF)

Milon Mondal, Helene Köster, Nedyalka Radeva, Costas Potamitis, Maria Zervou, Gerhard Klebe, Anna K. H. Hirsch

Substituent effects on rotary motion of molecular motor

ACF2013 C16    (PDF)

Jiawen Chen, Jort Robertus, Ben L. Feringa

Synthesis of selected porphyrins for NO-free regulation of sGC enzyme

ACF2013 C17    (PDF)

Sabina Pisarek, Dorota Gryko

Sequential polymorphic transformation assisted by dynamic covalent chemistry

ACF2013 C18    (PDF)

Ana M. Belenguer, Giulio I. Lampronti, Simon Redfern, Jeremy K. M. Sanders

Fluoroalkyl group transfer using phosphonates

ACF2013 C19    (PDF)

Petr Beier, Stanislav Opekar, Prabhakar Cherkupally

Structural Peculiarities and Catalytic Activity of Dibenzobarrelene-Based PCsp3P Pincer Iridium Complexes

ACF2013 C20    (PDF)

N.V. Belkova, G.A. Silantyev, O.A. Filippov, S. Musa, D. Gelman, L.M. Epstein, K. Weisz, E.S. Shubina

Molecular Origami: Oxonium-Ylide Rearrangements of Enzymatically Desymmetrized Glutarates

ACF2013 C21    (PDF)

Jan Deska, Benedikt Skrobo

Natural tetrapyrroles — just "click" it!

ACF2013 C22    (PDF)

Mikolaj Chrominski, Maksymilian Karczewski, Anna Zieleniewska, Dorota Gryko

Supramolecular control of selectivity in transition metal catalysis using ligands functionalized with an anion binding pocket

ACF2013 C23    (PDF)

Pawel Dydio, Joost N. H. Reek

Gold catalyzed synthesis of tetrahydrocarbazole derivatives through an intermolecular cycloaddition of vinyl indoles and N-allenamides

ACF2013 C24    (PDF)

Valentina Pirovano, Laura Decataldo, Rubén Vicente, Elisabetta Rossi

Synthesis & Reactivities of Divalent and Trivalent Nickel Complexes Based on Pincer Ligands

ACF2013 C25    (PDF)

Davit Zargarian

Effect of the catalyst (HZSM-5 and Ni-Mo-catalysts) grain size to the product yield, composition and contaminants during waste plastic pyrolysis

ACF2013 C26    (PDF)

N. Miskolczi, N. Borsodi, L. Bartha

Selective Catalytic Cross-Couplings with Organolithium Reagents

ACF2013 C27    (PDF)

Martín Fañanás-Mastral, Manuel Pérez, Pieter H. Bos, Alena Rudolph, Syuzanna R. Harutyunyan, Valentín Hornillos, Carlos Vila, Massimo Giannerini, Ben L. Feringa

Sterically Congested Boranes for Frustrated Lewis Pairs

ACF2013 C28    (PDF)

Hasan Mehdi, Ádám Gyömöre, Éva Dorkó, Tibor Soós

Poster presentations

BIMBOL as a multifunctional chiral catalyst in synthesis of both enantiomers of glutamic acid

ACF2013 PS017    (PDF)

K.V. Hakobyan, A.S. Saghyan, Yu.N. Belokon, V.I. Maleev, Z.T. Gugkaeva, Y.V. Samoilichenko, M.A. Moskalenko, A.V. Hakobyan

New General Synthesis of Substituted Imidazoles

ACF2013 PS046    (PDF)

Anahit Pews-Davtyan, Matthias Beller

Tackling the catalytic, enantioselective 1,2-addition of Grignard reagents to ketimines

ACF2013 PS051    (PDF)

Alaric Desmarchelier, Syuzanna R. Harutyunyan

Synthesis of new chiral ferrocenyl diphosphine ligands for application in catalytic asymmetric 1,2-addition of organometallics to ketones

ACF2013 PS052    (PDF)

Rik Oost, Syuzanna R. Harutyunyan

Asymmetric Amplification due to Differences in Phase Behaviour of Cu-Diphosphine Based Chiral Complexes

ACF2013 PS054A    (PDF)

Francesca Caprioli, Ashoka V. R. Madduri, Martin Lutz, Adriaan J. Minnaard, Syuzanna R. Harutyunyan

Catalytic asymmetric synthesis of chiral tetrahydroisoquinoline derivatives

ACF2013 PS054B    (PDF)

Francesca Caprioli, Syuzanna R. Harutyunyan

Design and development of proline-based autocatalytic system

ACF2013 PS056    (PDF)

Antonio Rizzo, Syuzanna R. Harutyunyan

Solvent-free synthesis of chromene derivatives via three-component reactions of N-heterocycles

ACF2013 PS057    (PDF)

Faramarz Rostami-Charati, Zinatossadat Hossaini

Surface Imprinting Approach for the Design of Virus Recognition Nanoparticles

ACF2013 PS059    (PDF)

Alessandro Cumbo Bernard Lorber, F.-X. Corvini Philippe, Wolfgang Meier, Patrick Shahgaldian

In situ Catalytic Generation of Allyl Copper Species and its Direct Use for Asymmetric Allylation

ACF2013 PS064    (PDF)

Yohei Shimizu, Prasanna Kumara Chikkade, Junya Kawai, Motomu Kanai

Chiral Polyols as Catalysts of Asymmetric C-C Bond Formation Reactions

ACF2013 PS065    (PDF)

Y.V. Samoilichenko, Z.T. Gugkaeva, V.I. Maleev, M.A. Moskalenko, A.T. Tsaloev, V.N. Khrustalev, K.V. Hakobyan, A.S. Peregudov, A.S. Saghyan, Y.N. Belokon

Novel amphiphilic compounds for construction of stimulus-sensitive liposomal containers

ACF2013 PS092    (PDF)

P.N. Veremeeva, V.L. Lapteva, V. A. Palyulin, I.V. Grishina, A. A. Yaroslavov, N. S. Zefirov

Quantitative monitoring of biphasic reactions using flow systems by Raman spectroscopy

ACF2013 PS093    (PDF)

D. Angelone, S. Abdolahzadeh, A. Varagnat, A.C. Dennis, J. W. de Boer, W. R. Browne

In Silico Design of New Selective Cyclooxygenase-2 (COX-2) Inhibitors

ACF2013 PS096A    (PDF)

D. Mohammad-Aghaie, Z. Jafari

Computer Design of Novel Alkylating-agents as Anti-Cancer Drugs

ACF2013 PS096B    (PDF)

D. Mohammad-Aghaie, M. N. Soltani Rad, M. Halvani

Isobutyl- and Aryloxyisobutylaluminoxanes as Activators for Zirconocene-based Catalytic Systems in Olefin Polymerization

ACF2013 PS098    (PDF)

E.E. Faingol'd, O.N. Babkina, S.L. Saratovskikh, A.N. Panin, N.M. Bravaya, E.A. Fushman

Membranotropic and Relaxation Properties of New Water Solubl Endometallofullerens

ACF2013 PS101    (PDF)

I.I. Faingold, D.A. Poletaeva, A.I. Kotelnikov, R.A. Kotelnikova, A.B. Kornev, P.A. Troshin, I.E. Careev, V.P. Bubnov, V.S. Romanova

Room temperature oxidation of alcohols and alkanes to ketones with H2O2 an in situ prepared catalyst

ACF2013 PS103    (PDF)

Francesco Mecozzi, Jia Jia Dong, Pattama Saisaha, Duenpen Unjareon, Emma C. Harvey, Dirk Pijper, Paul L. Alsters, Ruben P. van Summeren, Johannes W. de Boer, Ronald Hage, Ben L. Feringa, Wesley R. Browne

Anion templated dynamic combinatorial libraries based on reversible S-S bond formation

ACF2013 PS104    (PDF)

Filip Ulatowski, Janusz Jurczak

Development of Non-Hydrolysable Analogs of Phosphoinositol Polyphosphates

ACF2013 PS105    (PDF)

Igor Pavlović, Henning Jessen

Off-line reaction monitoring of the oxidation of alkenes in water at low concentrations using DROP COATING DEPOSITION RAMAN Spectroscopy

ACF2013 PS110    (PDF)

Shaghayegh Abdolahzadeh, Nicola M. Boyle, Apparao Draksharapu, Andrew C. Dennis, Ronald Hage, Johannes W. de Boer, Wesley R. Browne

Synthesis of cluster anion [B12H12]2— derivatives with B-OH reaction site for the subsequent modification in developing BNCT preparations

ACF2013 PS111    (PDF)

A. I. Ogarkov, A. S. Chernyavskiy, S. G. Sakharov, K. A. Solntsev

Vanadium-group metal nitrides ceramic materials prepared by oxidative constructing

ACF2013 PS112    (PDF)

A. V. Shokod'ko, A. A. Ashmarin, A. S. Chernyavskiy, K. A. Solntsev

Chemistry of α-Iminonitriles: Amidation of Aldehydes and Alcohols and Three-component Strecker /Thio-Michael Addition/ Hydrolysis to Access β-Mercaptoamides

ACF2013 PS115    (PDF)

Jean-Baptiste Gualtierotti, Xavier Schumacher, Patrice Fontaine, Géraldine Masson, Qian Wang, Jieping Zhu

Flow Assisted Synthesis of 2-Substituted-Indoles Employing Ceria Supported Mixed Metal Oxides

ACF2013 PS116    (PDF)

Benjamin N. Bhawal, Claudio Battilocchio, Steven V. Ley

Synthesis of Phosphoanhydrides by Selective Reaction of Phosphoramidites with Phosphates

ACF2013 PS118    (PDF)

Alexandre Hofer, Gregor S. Cremosnik, Henning J. Jessen

Static combinatorial chemistry: macrocyclization via high pressure duble-amidation reactions

ACF2013 PS120    (PDF)

Grzegorz Pikus, Janusz Jurczak

Simple Dynamic Combinatorial Libraries in the search for novel selective anion receptors

ACF2013 PS121    (PDF)

Agnieszka Sadowska-Kuziola, Filip Ulatowski, Janusz Jurczak

Role of solvent-ligand exchange in the reaction of iron(II) polypyridyl complexes with H2O2

ACF2013 PS122    (PDF)

Sandeep K. Padamati, D. Unjaroen, A. Draksharapu, W. R. Browne

Design, synthesis and pharmacological evaluation of new Rac1 protein inhibitors

ACF2013 PS128    (PDF)

Alessandro Ruffoni, Francesca Clerici, Alessandro Contini, Nicola Ferri

Progress towards the Total Syntheses of Rubriflordilactones A and B

ACF2013 PS130    (PDF)

Shermin S. Goh, Birgit Gockel, Hannah Baars, Edward A. Anderson

Chiral macrocycles and molecular cages based on trans-(1R,2R)-diaminocyclohexane. Synthesis, structure and their chirooptical properties

ACF2013 PS134    (PDF)

Małgorzata Petryk, Agnieszka Janiak, Marcin Kwit

Application of 2-methyltetrahydrofuran as a "green solvent" in olefin metathesis reactions

ACF2013 PS142    (PDF)

Michal Smoleń, Mariusz Kedziorek, Karol Grela

Direct Catalytic Cross-Coupling of Organolithium Compounds

ACF2013 PS147    (PDF)

Massimo Giannerini, Martín Fañanás-Mastral, Ben L. Feringa

Factors affecting self-assembly of a covalent organic cage

ACF2013 PS148    (PDF)

Pawel Skowronek, Beata Warzajtis, Urszula Rychlewska, Jacek Gawroński

Synthesis and self-assembly of interdigitating amphiphiles

ACF2013 PS149    (PDF)

Peter Stacko, Derk Jan van Dijken, Marc C. A. Stuart, Ben L. Feringa

Synthesis of Optically Active β- or γ-Alkyl Substituted Alcohols through Copper-Catalyzed Asymmetric Allylic Alkylation with Organolithium Reagents

ACF2013 PS150    (PDF)

Sureshbabu Guduguntla, Martín Fañanás-Mastral, Ben L. Feringa

Towards breaking of coordination bonds by light-driven molecular motors

ACF2013 PS152    (PDF)

Thomas van Leeuwen, Ben L. Feringa

Pichia glucozyma: a powerful biocatalyst for enantioselective reduction of ketones

ACF2013 PS155    (PDF)

Martina Contente, Diego Romano, Francesco Molinari, Andrea Pinto, Lucia Tamborini, Paola Conti

Reactive Sulfur Species: From natural product research to applications in Medicine and Agriculture

ACF2013 PS156    (PDF)

Uma M.Viswanathan, Brigitte Czepukojc, Thomas Schneider, Torsten Burkholz, Claus Jacob, Shiraz Markarian

One-Pot Catalytic Conversion of Organosolv Lignin, Cellulose and of Woody Biomass to Liquid Fuels

ACF2013 PS157    (PDF)

Katalin Barta, Theodore D. Matson, Alexei. V. Iretskii, Peter C. Ford

Enantioselective synthesis of quaternary stereogenic centers via Copper Catalyzed Allylic Alkylation with organolithium compounds

ACF2013 PS158    (PDF)

Romina Vitale, Martín Fañanás-Mastral, Manuel Pérez, Ben L. Feringa

Self-assembly of light-harvesting crystalline nanosheets in aqueous media

ACF2013 PS160    (PDF)

Jonathan Baram, Chen Shahar, Haim Weissman, Sidney R. Cohen, Boris Rybtchinski

Catalytic asymmetric synthesis of chiral tertiary α-hydroxysilanes

ACF2013 PS163    (PDF)

Jiawei Rong, Rik Oost, Syuzanna R. Harutyunyan

Towards new photoswitchable organocatalysts

ACF2013 PS165    (PDF)

Thomas Neubauer, Ben L. Feringa

Synthesis of enantiopure (P)-[5]- and (P,P)-Bis-[5]-Helicenequinones Joined by Aryl or Ferrocenyl Linkers Via Click Chemistry

ACF2013 PS168    (PDF)

Ana M. del Hoyo, Alfonso Latorre, Antonio Urbano, M. Carmen Carreño

Asymmetric synthesis of enantiomerically enriched (S)-α-aminopropionic acids containing more than one heteroatom in the side-chain radical

ACF2013 PS170    (PDF)

A.S. Saghyan, A.S. Dadayan, S.G. Petrosyan, H.M. Simonyan, A.V. Geolchanyan, H.R. Zurnachyan, A.F. Mkrtchyan, G.M. Mkrtchyan

Deuteriated Tetraalkylstannanes and Covalent Trialkylstannyl Salts and an Examination of their Adsorption on Gold

ACF2013 PS171    (PDF)

Jan Hajduch, Anna Kohutová, Eva Kaletová, Josef Michl

Dielectric relaxation of dimethylsulfone in water-dimethylsulfoxide solutions

ACF2013 PS176    (PDF)

L.S. Gabrielyan, S.A. Markarian, H. Weingärtner

Novel potential biologically active of sulfur-containing vicinal amino alcohols: Synthesis and activity

ACF2013 PS177    (PDF)

A. S. Galstyan, E. A. Shirinyan, I. L. Bazukyan

The Study of Hemoglobin — Tannic Acid Interactions by Fluorescence Spectroscopy Method

ACF2013 PS178    (PDF)

Karine R. Grigoryan, Levon S. Sargsyan

Volumetric and transport properties of AOT/n-heptane/DMSO-water reverse micellar systems

ACF2013 PS183    (PDF)

H.R. Sargsyan, G.A. Shahinyan, S.A. Markarian

Interaction of Benz-Substituted 2-Chloro-4-Methylquinolines with 2-Mercaptoaniline

ACF2013 PS186    (PDF)

I. L. Aleksanyan, L. P. Hambardzumyan

Scientific Basis of Targeted Synthesis of Inorganic Multicomponent Systems

ACF2013 PS187    (PDF)

A. B. Niyazbekova, N. V. Akatyev, M. M. Mukasheva, N. K. Aimurzina

The new transformations of 3-substituted-1,2,4-triazoles

ACF2013 PS188    (PDF)

T. V. Ghochikyan, M. A. Samvelyan, V. S. Harutyunyan, E. V. Harutyunyan, A. E. Kotsinyan, Peter Langer

2-Propyl- and 4-Butadienyl-S-Functionally Substituted Phosphonium Salts. Unusual Behaviour of 1,4-bis(Buta-1,3-diene)Phosphonium Salts in Reaction

ACF2013 PS191    (PDF)

M. Zh. Ovakimyan, G. Ts. Gasparyan, A. S. Poghosyan, M. R. Grigoryan, A. S. Bichakhchyan

Synthesis of peptides containing (S)-2-amino-3-[4-allyl-(3-pyridine-4`-yl)- and (3-pyridine-3`-yl)-5-thioxo-1,2,4-triazol-1-yl]-propionic acids

ACF2013 PS194    (PDF)

V. T. Danghyan, T. O. Sargsyan, S. M. Jamgaryan, E. A. Gyulumyan, Yu. M. Danghyan, A. S. Saghyan

Synthesis and Anticonvulsant Activity of Amino Derivatives of Cyclopenta[4',5']Pyrimido[3',2':4,5]Thieno[3,2-d]Pyrimidines

ACF2013 PS195    (PDF)

Sh. Sh. Dashyan, E. G. Paronikyan, A. S. Noravyan, I. A. Dzhagatspanyan, I. M. Nazaryan, A. G. Akopyan

New Approach to the Syntheses of Derivatives of Natural Compound Dihydroactinidiolide

ACF2013 PS197    (PDF)

Anna Hovhannisyan, Gagik Melikyan

Helichrysum Rubicundum as a possible raw material for the "Flamin" drug

ACF2013 PS200    (PDF)

H. S. Ananikyan, V. A. Mnatsakanyan

The magnitude of the positive charge of the reaction initiator and the selectivity

ACF2013 PS201A    (PDF)

K. H. Petrosyan

Forecasts of halogen reactivity under the light of acid-base theory

ACF2013 PS201B    (PDF)

K. H. Petrosyan, N. S. Dshkhunyan

3-(Dichloroacetyl)chromone; A New Building Block for the Synthesis of Formylated Purine Isosteres

ACF2013 PS204    (PDF)

Ani Hakobyan, Peter Langer, Viktor O. Iaroshenko, Satenik Mkrtchyan, Vahuni Karapetyan, Alexander Villinger, Karine Hakobyan

The expansion of the area of application of base-catalyzed intramolecular cyclization of quaternary ammonium salts

ACF2013 PS205    (PDF)

E. O. Chukhajyan, K. G. Shahkhatuni, L. V. Ayrapetyan

Malonodinitrile - A Lonza success story

ACF2013 PS207    (PDF)

Albrecht Metzger, Anna-Christina Hormes, et al.

Polymer-mineral packing materials for RP-HPLC

ACF2013 PS208    (PDF)

S. S. Hayrapetyan, L. G. Mangasaryan, L. S. Hayrapetyan, H. G. Khachatryan

Peptides — inhibitors of collagenase

ACF2013 PS210    (PDF)

N. A. Hovhannisyan, A. S. Sargsyan, M. B. Chitchyan, M. A. Melkumyan, G. G. Oganezova, N. S. Avetisyan, A. M. Hovhannisyan, Yu. M. Danghyan